Publications

Department of Chemistry




Publications

Publications in Peer-Review Journals
 
125.
M. Naimi, Th. Tsakiridis, Th. C. Stamatatos, D. I. Alexandropoulos, E. Tsiani. Increased skeletal muscle glucose uptake by rosemary extract through AMPK activation. Biochemical and Biophysical Research Communications, submitted for publication.
124.
P. S. Perlepe, A. A. Athanasopoulou, K. I. Alexopoulou, C. P. Raptopoulou,V. Psycharis,A. Escuer, S. P. Perlepes, Th. C. Stamatatos. Structural and magnetic variations in tetranuclear NiII clusters: the effect of the reaction solvent and ligand substitution on the product identity. Dalton Transactions, submitted for publication.
123.
D. Dermitzaki, C. P. Raptopoulou,V. Psycharis,A. Escuer, S. P. Perlepes, Th. C. Stamatatos. Unexpected metal ion-assisted transformations leading to unexplored bridging ligands in NiII coordination chemistry: The case of PO3F2- group. Dalton Transactions, article in press.
122.
D. I. Alexandropoulos, L. Cunha-Silva, A. Escuer, Th. C. Stamatatos. New classes of ferromagnetic materials with exclusively end-on azido bridges: From SMMs to 2-D molecule-based magnets. Chemistry - A European Journal, article in press.
121.
B. Murphy, I. Šnajdr, A. Machara, M. A. A. Endoma-Arias, Th. C. Stamatatos, D. P. Cox, T. Hudlický. Conversion of thebaine to oripavine and other useful intermediates for the semisynthesis of opiate-derived agents: Synthesis of hydromorphone. Advanced Synthesis and Catalysis, article in press.
120.
M. Charalambous, S. M. Zartilas, E. E. Moushi, C. Papatriantafyllopoulou, M. J. Manos, Th. C. Stamatatos, S. Mukherjee, V. Nastopoulos, G. Christou, A. J. Tasiopoulos. Discrete and encapsulated molecular grids: Homometallic Mn15 and heterometallic Mn24Ni2 aggregates. Chemical Communications, 50, 9090-9093, 2014.
119.
R. Mirabdolbaghi, T. Dudding, Th. C. Stamatatos. A class of phase-transfer catalyst with interionic strain: Insight into the bonding of disubstituted N- vs carbene-stabilized NI-centered cations. Organic Letters, 16, 2790-2793, 2014.
118.
E. C. Mazarakioti, K. M. Poole,L. Cunha-Silva,G. Christou, Th. C. Stamatatos. A new family of Ln7 clusters with an ideal D3h metal-centered trigonal prismatic geometry, and SMM and photoluminescence behaviors. Dalton Transactions, 43, 11456-11460, 2014. Hot article for Dalton Transactions in May 2014: http://blogs.rsc.org/dt/2014/05/01/hot-articles-for-may/
117.
D. I. Alexandropoulos, A. Fournet,L. Cunha-Silva, A. M. Mowson,V. Bekiari, G. Christou, Th. C. Stamatatos. Fluorescent naphthalene diols as bridging ligands in LnIII cluster chemistry: Synthetic, structural, magnetic and photophysical characterization of LnIII8 ‘Christmas-stars’. Inorganic Chemistry, 53, 5420-5422, 2014.
116.
A. A. Athanasopoulou, C. P. Raptopoulou,A. Escuer, Th. C. Stamatatos. Rare nuclearities in Ni(II) cluster chemistry: A Ni11 cage-like cluster from the initial use of N-salicylidene-2-amino-5-chlorobenzoic acid. RSC Advances, 4, 12680-12684, 2014.
115.
E. Gavey, Y. Beldjoudi, J. M. Rawson, Th. C. Stamatatos, M. Pilkington. Slow relaxation in the first penta-aza Dy(III) macrocyclic complex. Chemical Communications, 50, 3741-3743, 2014
114.
A. Escuer, J. Esteban, S. P. Perlepes, Th. C. Stamatatos. The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry. Coordination Chemistry Reviews, 275, 87-129, 2014.
113.
D. I. Alexandropoulos,L. Cunha-Silva,L. Pham, V. Bekiari, G. Christou, Th. C. Stamatatos. Tetranuclear lanthanide(III) complexes with a zigzag topology from the use of pyridine-2,6-dimethanol: Synthetic, structural, spectroscopic, magnetic and photoluminescence studies. Inorganic Chemistry, 53, 3220-3229, 2014.
112.
D. P. Giannopoulos, A. Thuijs, W. Wernsdorfer, M. Pilkington, G. Christou, Th. C. Stamatatos. Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets. Chemical Communications, 50, 779-781, 2014. Inside Cover.
111.
D. I. Alexandropoulos, A. M. Mowson,M. Pilkington,V. Bekiari, G. Christou, Th. C. Stamatatos. Emissive molecular nanomagnets: Introducing optical properties in triangular oximato {MnIII3} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues. Dalton Transactions, 43, 1965-1969, 2014. Front Cover.
110.
D. Dermitzaki, G. Lorusso, C. P. Raptopoulou,V. Psycharis,A. Escuer, M. Evangelisti, S. P. Perlepes, Th. C. Stamatatos. Molecular nanoscale magnetic refrigerants: A ferrimagnetic {CuII15GdIII7} cage-like cluster from the use of pyridine-2,6-dimethanol. Inorganic Chemistry, 52, 10235-10237, 2013.
109.
S. Zartilas, C. Papapatriantafyllopoulou, Th. C. Stamatatos, V. Nastopoulos, E. Cremades, E. Ruiz, G. Christou, C. Lampropoulos, A. J. Tasiopoulos. A MnII6MnIII6 single-strand molecular wheel with a reuleaux triangular topology: Synthesis, structure, magnetism and DFT studies. Inorganic Chemistry, 52, 12070-12079, 2013.
108.
D. I. Alexandropoulos, C. Li, C. P. Raptopoulou, V. Psycharis, W. Wernsdorfer, G. Christou, Th. C. Stamatatos. Slow magnetization relaxation in a 1-D double-chain coordination polymer composed of {DyIII4} repeating units. Current Inorganic Chemistry, 3, 161-171, 2013. Highlighted in Molecular Magnetism Web (http://www.molmag.de/) under the title: “Emerging young scientists in molecular magnetism”.
107.
D. I. Alexandropoulos, E. C. Mazarakioti, S. J. Teat, Th. C. Stamatatos. Rare nuclearities, new structural motifs, and slow magnetization relaxation phenomena in manganese cluster chemistry: A Mn15Na2 cage from the use of triethanolamine/pivalate/azide blend. Polyhedron, 64, 91-98, 2013.
106.
D. I. Alexandropoulos, T. N. Nguyen,L. Cunha-Silva, Th. F. Zafiropoulos, A. Escuer, G. Christou, Th. C. Stamatatos. Slow magnetization relaxation in unprecedented MnIII4DyIII3 and MnIII4DyIII5 clusters from the use of N-salicylidene-o-aminophenol. Inorganic Chemistry, 52, 1179-1181, 2013.
105.
E. S. Koumousi, A. Routzomani, T. N. Nguyen,D. P. Giannopoulos, C. P. Raptopoulou, V. Psycharis, G. Christou, Th. C. Stamatatos. 2-Pyrrolyloximes in high-nuclearity transition-metal cluster chemistry: Fe10 and Fe12. Inorganic Chemistry, Inorganic Chemistry, 52, 1176-1178, 2013.
104.
D. I. Alexandropoulos, C. Papatriantafyllopoulou,C. Li,L. Cunha-Silva, M. J. Manos, A. J. Tasiopoulos, W. Wernsdorfer, G. Christou, Th. C. Stamatatos. Approaches to molecular magnetic materials from the use of cyanate groups in higher oxidation state metal cluster chemistry: Mn14 and Mn16. European Journal of Inorganic Chemistry, 2286-2290, 2013.
103.
K. F. Konidaris, M. Giouli, C. P. Raptopoulou, V. Psycharis,I. I. Verginadis, A. Vasiliadis, A. S. Afendra, S. Karkabounas, E. Manessi-Zoupa, Th. C. Stamatatos. Employment of pyridyl oximes and dioximes in zinc(II) chemistry: Synthesis, structural and spectroscopic characterization, and biological evaluation. Inorganica Chimica Acta, 396, 49-59, 2013.
102.
E. Katsoulakou, D. Dermitzaki, K. F. Konidaris, E. E. Moushi, C. P. Raptopoulou, V. Psycharis, A. J. Tasiopoulos, V. Bekiari, E. Manessi-Zoupa, S. P. Perlepes, Th. C. Stamatatos. Hexanuclear zinc(II) carboxylate complexes from the use of pyridine-2,6-dimethanol: Synthetic, structural and photoluminescence studies. Polyhedron, 52, 467-475, 2013.
101.
Th. C. Stamatatos, S. P. Perlepes, C. P. Raptopoulou, A. Terzis, N. Klouras. Bis(aquo)bis(η5-cyclopentadienyl)vanadium(IV) bis(trifluoromethanesulfonate) tetrahydrofuran solvate: Synthesis and characterization. Inorganica Chimica Acta, 394, 747-751, 2013.
100.
K. I. Alexopoulou, C. P. Raptopoulou, V. Psycharis, A. Terzis, V. Tangoulis, Th. C. Stamatatos,S. P. Perlepes. Solvent-dependent access to two different NiII4 core topologies from the first use of pyridine-2,6-dimethanol in nickel(II) cluster chemistry. Australian Journal of Chemistry, 65, 1608-1619, 2012.
99.
E. S. Koumousi, M. Zampakou, C. P. Raptopoulou, V. Psycharis, C. M. Beavers, S. J. Teat, G. Psomas, Th. C. Stamatatos. First palladium(II) and platinum(II) complexes from employment of 2,6-diacetylpyridine dioxime: Synthesis, structural and spectroscopic characterization, and biological evaluation. Inorganic Chemistry, 51, 7699-7710, 2012.
98.
D. I. Alexandropoulos, M. J. Manos, C. Papatriantafyllopoulou,S. Mukherjee,A. J. Tasiopoulos, S. P. Perlepes, G. Christou, Th. C. Stamatatos. Squaring the clusters: A MnIII4Ni4 molecular square from nickel(II)-induced structural transformation of a MnII/III/IV12 cage. Dalton Transactions, 41, 4744-4747, 2012.
97.
Th. C. Stamatatos, G. Vlahopoulou, C. P. Raptopoulou, V. Psycharis, A. Escuer, G. Christou, S. P. Perlepes. Single-strand molecular wheels and coordination polymers in copper(II) benzoate chemistry from the employment of α-benzoin oxime and azides: Synthesis, and structural and magnetic characterization. European Journal of Inorganic Chemistry, 3121-3131, 2012.
96.
S. Mukherjee, J. A. Stull, J. Yano, Th. C. Stamatatos, K. Pringouri, T. A. Stich, K. A. Abboud, R. D. Britt, V. K. Yachandra, G. Christou. Synthetic model of the [Mn3CaO4] cubane core of the oxygen-evolving complex of photosystem II. Proceedings of the National Academy of Sciences, 109, 2257-2262, 2012.
95.
Th. C. Stamatatos, R. Adam, C. P. Raptopoulou, V. Psycharis, R. Ballesteros, B. Abarca, S. P. Perlepes, A. K. Boudalis. The first member of a second generation family of ligands derived from metal-ion assisted reactivity of di-2,6-(2-pyridylcarbonyl)pyridine: Synthesis and characterization of a MnII/III4 rhombus. Inorganic Chemistry Communications, 15, 73-77, 2012.
94.
D. I. Alexandropoulos, S. Mukherjee,C. Papatriantafyllopoulou, C. P. Raptopoulou, V. Psycharis, V. Bekiari, G. Christou, Th. C. Stamatatos. A new family of nonanuclear lanthanide clusters displaying magnetic and optical properties. Inorganic Chemistry, 50, 11276-11278, 2011.
93.
E. S. Koumousi, S. Mukherjee, C. M. Beavers, S. J. Teat, G. Christou, Th. C. Stamatatos. Towards models of the oxygen-evolving complex (OEC) of photosystem II: A Mn4Ca cluster of relevance to low oxidation states of the OEC. Chemical Communications, 47, 11128-11130, 2011.
92.
K. F. Konidaris, V. Bekiari, E. Katsoulakou, C. P. Raptopoulou, V. Psycharis, S. P. Perlepes, Th. C. Stamatatos, E. Manessi-Zoupa. Initial employment of pyridine-2-amidoxime in zinc(II) chemistry: synthetic, structural and spectroscopic studies of mononuclear and dinuclear complexes. Inorganica Chimica Acta, 376, 470-478, 2011.
91.
Th. C. Stamatatos, S. P. Perlepes, M. J. Manos, A. J. Tasiopoulos, N. Klouras. Unexpected formation, X-ray structure, and characterization of the triangular [Ti3Ο(OMe)6(η5-C5H5)3](I3) complex from hydrolysis and methanolysis of [Ti(η5-C5H5)2I2]. Journal of Coordination Chemistry, 64, 2377-2387, 2011.
90.
Th. C. Stamatatos, K. Oliver, K. A. Abboud, G. Christou, Synthetic entry into mixed bismuth-manganese cluster chemistry at high oxidation states: BiIII2MnIV6 and BiIIIMnIII10­ complexes, Inorganic Chemistry, 50, 5272-5282, 2011.
89.
Th. C. Stamatatos, C. P. Raptopoulou, S. P. Perlepes, A. K. Boudalis. The first non-acetato members of the bis(anion)octacarboxylatotetrakis{di-2-pyridyl-methanediolate(-2)}enneametal(II) family of complexes: Synthesis, X-ray structures and magnetism of [M9(N3)2(O2CCMe3)8{(py)2CO2}4] (M = Co, Ni). Polyhedron, 30, 3026-3033, 2011.
88.
C. R. Bowers, C.- Y. Cheng, Th. C. Stamatatos, G. Christou, Hyperpolarized NMR in single-file nanotubes. AIP Conference Proceedings, 1330, 43-46, 2011.
87.
Th. C. Stamatatos, S. P. Perlepes, C. P. Raptopoulou, V. Psycharis, N. Klouras. Reactions of the metallocene dichlorides [M(Cp)2Cl2] (M=Zr, Hf) and [Ti(MeCp)2Cl2] with the pyridine-2,6-dicarboxylate(-2) ligand: Synthesis, spectroscopic characterization and X-ray structures of the products. Polyhedron, 30, 451-457, 2011.
86.
C. Papatriantafyllopoulou, Th. C. Stamatatos, W. Wernsdorfer, S. J. Teat, A. J. Tasiopoulos, A. Escuer, S. P. Perlepes. Combining azide, carboxylate and 2-pyridyloximate ligands in transition metal chemistry: Ferromagnetic NiII5 clusters with a bowtie skeleton. Inorganic Chemistry, 49, 10486-10496, 2010.
85.
C. G. Efthymiou, Th. C. Stamatatos, C. Papatriantafyllopoulou, A. J. Tasiopoulos, W. Wernsdorfer, S. P. Perlepes, G. Christou, Nickel/lanthanide single-molecule magnets: {Ni3Ln} ‘stars’ with a ligand derived from the metal-promoted reduction of di-2-pyridyl ketone under solvothermal conditions.  Inorganic Chemistry, 49, 9737-9739, 2010.
84.
C. Papatriantafyllopoulou, Th. C. Stamatatos, C. G. Efthymiou, L. Cunha-Silva, F. A. Almeida Paz, S. P. Perlepes, G. Christou. A high nuclearity 3d/4f metal oxime cluster: An unusual Ni8Dy8 ‘core-shell’ complex from the use of 2-pyridinealdoxime, Inorganic Chemistry, 49, 9743-9745, 2010.
83.
Th. C. Stamatatos, D. Foguet-Albiol, W. Wernsdorfer,K. A. Abboud, G. Christou. High-nuclearity, mixed-valence Mn17, Mn18 and {Mn62}ncomplexes from the use of triethanolamine. Chemical Communications, 274-276, 2010.
82.
K. F. Konidaris, A. Terzis, C. P. Raptopoulou, S. P. Perlepes, E. Manessi-Zoupa, Th. C. Stamatatos. Use of the 2-pyridinealdoxime/N,N′-donor ligand combination in cobalt(III) chemistry: Synthesis and crystal structure determination of mononuclear Co(III) complexes. Bioinorganic Chemistry and Applications, doi:10.1155/2010/159656.
81.
D. M. Pajerowski, Th. C. Stamatatos, S. Mukherjee, E. S. Knowles, M. Bencomo, M. W. Meisel, G. Christou. Pressure dependence of the magnetization in Mn7 single-molecule magnets. Polyhedron, 29, 2462-2464, 2010.
80.
Th. C. Stamatatos, K. A. Abboud, G. Christou. A family of 3-D coordination polymers composed of mixed-valence Mn6 octahedra within Na4 tetrahedra. Journal of Cluster Science, 21, 485-501, 2010.
79.
E. Koleros, Th. C. Stamatatos, V. Psycharis, C. P. Raptopoulou, S. P. Perlepes, N. Klouras. In search for titanocene complexes with improved cytotoxic activity: Synthesis, x-ray structure and spectroscopic study of bis(η5-cyclopentadienyl)difluorotitanium(IV). Bioinorganic Chemistry and Applications, doi:10.1155/2010/914580.
78.
D. I. Alexandropoulos, C. Papatriantafyllopoulou, O. Roubeau,S. J. Teat, S. P. Perlepes, G. Christou,Th. C. Stamatatos. The highest nuclearity manganese/oximate complex: An unusual MnII/III15 cluster with an S = 6 ground state. Inorganic Chemistry, 49, 3962-3964, 2010.
77.
E. S. Koumousi, M. J. Manos,C. Lampropoulos, A. J. Tasiopoulos, W. Wernsdorfer, G. Christou,Th. C. Stamatatos. α-Benzoin oxime in higher oxidation state 3d metal cluster chemistry: Structural and magnetic study of a new MnIII9 complex, Inorganic Chemistry, 49, 3077-3079, 2010.
76.
C.- Y. Cheng, Th. C. Stamatatos, G. Christou, C. R. Bowers, Molecular wheels as nanoporous materials: Differing modes of gas diffusion through Ga10 and Ga18 wheels of different diameters probed by hyperpolarized 129Xe NMR spectroscopy. Journal of the American Chemical Society, 132, 5387-5393, 2010.
75.
C. Lampropoulos, Th. C. Stamatatos, M. J. Manos, A. J. Tasiopoulos, K. A. Abboud, G. Christou. New mixed-valence MnII/III6 complexes bearing oximato and azido ligands: Synthesis, and structural and magnetic characterization, European Journal of Inorganic Chemistry, 2244-2253, 2010.
74.
T.- F. Liu, Th. C. Stamatatos, K. A. Abboud, G. Christou. An alcoholysis route to a Cu16 cluster, and the influence of the alcohol. Dalton Transactions, 3554-3556, 2010.
73.
E. S. Koumousi, C. P. Raptopoulou, S. P. Perlepes, A. Escuer, Th. C. Stamatatos. Strong antiferromagnetic coupling in doubly N,O oximato-bridged dinuclear copper(II) complexes. Polyhedron, 29, 204-211, 2010.
72.
Th. C. Stamatatos, D. Foguet-Albiol,K. M. Poole,W. Wernsdorfer, K. A. Abboud, T. A. O’Brien, G. Christou. Spin maximization from S = 11 to S = 16 in Mn7 disk-like clusters: Spin frustration effects and their computational rationalization, Inorganic Chemistry, 48, 9831-9845, 2009.
71.
G. Redler, C. Lampropoulos, S. Datta, C. Koo, Th. C. Stamatatos, N. E. Chakov, G. Christou, S. Hill. Crystal lattice desolvation effects on the magnetic quantum tunneling of single-molecule magnets. Physical Review B, 80, 094408, 2009.
70.
Th. C. Stamatatos, C. G. Efthymiou, C. C. Stoumpos, S. P. Perlepes. Adventures in the coordination chemistry of di-2-pyridyl ketone and related ligands: From high-spin molecules and single-molecule magnets to coordination polymers, and from structural aesthetics to an exciting new reactivity chemistry of coordinated ligands, European Journal of Inorganic Chemistry, 3361-3391, 2009.
69.
G. C. Vlahopoulou, D. I. Alexandropoulos, C. P. Raptopoulou, S. P. Perlepes, A. Escuer, Th. C. Stamatatos. A tetranuclear complex from the employment of pyridine-2,6-dimethanol in copper(II) nitrate chemistry: Synthetic, structural and magnetic studies. Polyhedron, 28, 3235-3242, 2009.
68.
E. E. Moushi, Th. C. Stamatatos,V. Nastopoulos,G. Christou, A. J. Tasiopoulos. A new family of octanuclear Mn complexes with a rod-like topology. Polyhedron, 28, 3203-3208, 2009.
67.
E. E. Moushi, Th. C. Stamatatos,V. Nastopoulos,G. Christou, A. J. Tasiopoulos. 1-D coordination polymers consisting of a high-spin Mn17 octahedral unit. Polyhedron, 28, 1814-1817, 2009.
66.
C. Lampropoulos, Th. C. Stamatatos, K. A. Abboud, G. Christou, A convenient MnIII starting material for the synthesis of homo- and heterometallic manganese carboxylate clusters: Mn9 and Mn10-xFex complexes. Polyhedron, 28, 1958-1964, 2009.
65.
Th. C. Stamatatos, K. A. Abboud, G. Christou. Old ligands with new coordination chemistry: A Mn17Na cluster bearing triethanolamine and azide groups and exhibiting slow magnetization relaxation. Polyhedron, 28, 1880-1882, 2009.
64.
Th. C. Stamatatos, K. V. Pringouri, K. A. Abboud, G. Christou, High-spin molecules: A mixed-valence Mn6 octahedron with an S = 11 ground state.  Polyhedron, 28, 1624-1627, 2009.
63.
Th. C. Stamatatos, J. C. Vlahopoulou, V. Tangoulis,C. P. Raptopoulou, A. Terzis, G. S. Papaefstathiou,S. P. Perlepes. New copper(II) clusters and coordination polymers from the amalgamation of azide/benzoate/di-2-pyridyl ketone ligands, Polyhedron, 28, 1656-1663, 2009.
62.
Th. C. Stamatatos, E. Katsoulakou, A. Terzis, C. P. Raptopoulou, R. E. P. Winpenny, S. P. Perlepes. A family of mononuclear CoIII/2-pyridyloximate complexes and their conversion to trinuclear, mixed-valence linear CoII/III3 clusters. Polyhedron, 28, 1638-1645, 2009.
61.
E. E. Moushi, Th. C. Stamatatos,W. Wernsdorfer, V. Nastopoulos,G. Christou, A. J. Tasiopoulos. A Mn17 octahedron with a giant ground-state spin: Occurrence in discrete form and as multidimensional coordination polymers, Inorganic Chemistry, 48, 5049-5051, 2009.
60.
Th. C. Stamatatos, A. Vinslava, K. A. Abboud, G. Christou. Azide groups in high oxidation state Mn carboxylate chemistry: A new Mn11 complex and its conversion to a Mn25 azide complex with Me3SiN3. Chemical Communications, 2839-2841, 2009.
59.
G. C. Vlahopoulou, Th. C. Stamatatos, V. Psycharis, S. P. Perlepes, G. Christou. Initial employment of α-benzoin oxime as a route to high-nuclearity metal clusters: Decanuclear CuII complexes with a wheel topology. Dalton Transactions, 3646-3649, 2009.
58.
O. Waldmann, Th. C. Stamatatos, I. Sheikin, H. Mutka, H. U. Güdel, G. Christou. Quantum phase interference and Néel vector tunneling in antiferromagnetic molecular wheels. Physical Review Letters, 102, 157202, 2009.
57.
Th. C. Stamatatos, G. C. Vlahopoulou,C. P. Raptopoulou, A. Terzis, A. Escuer,S. P. Perlepes. Interpretation of the magnetic properties of a compound consisting of cocrystallized CuII3 and CuII4 clusters through the targeted synthesis and study of its discrete CuII4 component. Inorganic Chemistry, 48, 4610-4612, 2009.
56.
Th. C. Stamatatos, S. P. Perlepes, C. P. Raptopoulou, V. Psycharis, C. S. Patrickios, A. J. Tasiopoulos, A. K. Boudalis. Initial use of 1,1′-oxalyldiimidazole for inorganic synthesis: Decomposition of the ligand as a means to the preparation of an imidazole- and oxalate(-2)-containing, 1D copper(II) complex, Inorganic Chemistry Communications, 12, 402-405, 2009.
55.
Th. C. Stamatatos, S. P. Perlepes, C. P. Raptopoulou, A. Terzis, C. S. Patrickios, A. J. Tasiopoulos, A. K. Boudalis, Alcoholysis/hydrolysis of 1,1′-carbonyldiimidazole as a means to the preparation of unprecedented, imidazole-containing one-dimensional coordination polymers of copper(II). Dalton Transactions, 3354-3362, 2009.
54.
G. Lazari, Th. C. Stamatatos, C. P. Raptopoulou, V. Psycharis, M. Pissas, S. P. Perlepes, A. K. Boudalis. A metamagnetic 2D copper(II)-azide complex with 1D ferromagnetism and a hysteretic spin-flop transition. Dalton Transactions, 3215-3221, 2009.
53.
Th. C. Stamatatos, G. Christou. Azide groups in higher oxidation state manganese cluster chemistry: From structural aesthetics to single-molecule magnets, Inorganic Chemistry, 48, 3308-3322, 2009.
52.
C. Lampropoulos, K. A. Abboud, Th. C. Stamatatos, G. Christou, A nontwisted, ferromagnetically coupled MnIII3O triangular complex from the use of 2,6-bis(hydroxymethyl)-p-cresol, Inorganic Chemistry, 48, 813-815, 2009.
51.
C. C. Stoumpos, Th. C. Stamatatos, H. Sartzi, O. Roubeau, A. J. Tasiopoulos, V. Nastopoulos, S. J. Teat, G. Christou, S. P. Perlepes, Employment of methyl 2-pyridyl ketone oxime in manganese non-carboxylate chemistry: MnII2MnIV and MnII2MnIII6 complexes, Dalton Transactions, 1004-1015, 2009.
50.
Th. C. Stamatatos, K. A. Abboud,W. Wernsdorfer, G. Christou, {Mn6}n single-chain magnet bearing azides and di-2-pyridylketone-derived ligands. Inorganic Chemistry, 48, 807-809, 2009.
49.
C. Lampropoulos, Th. C. Stamatatos, K. A. Abboud, G. Christou, Initial use of dioximate ligands in 3d/4f cluster chemistry: Synthesis, structure, and magnetic studies of an unusual [GdIII2MnIVO]8+ complex. Inorganic Chemistry, 48, 429-431, 2009.
48.
Th. C. Stamatatos, S. J. Teat, W. Wernsdorfer, G. Christou, Enhancing the quantum properties of manganese-lanthanide single-molecule magnets: Observation of quantum tunneling steps in the hysteresis loops of a {Mn12Gd} cluster. Angewandte Chemie, International Edition, 48, 521-524, 2009.
47.
Th. C. Stamatatos, K. A. Abboud, G. Christou. A mononuclear MnIII/‘bis-tris’ complex and its conversion to a mixed-valence MnII/III5 cluster. Dalton Transactions, 41-50, 2009.
46.
Th. C. Stamatatos, S. Mukherjee,K. A. Abboud, G. Christou. The largest single-strand molecular wheel: Ga20 from a targeted, diolate-induced size modification of the Ga10 ‘gallic wheel’, Chemical Communications, 62-64, 2009.
45.
J. J. Henderson, C. M. Ramsey, E. del Barco, Th. C. Stamatatos, G. Christou. Control of the inhomogeneity degree by magnetic dilution in crystals of antiferromagnetic molecular rings. Physical Review B, 78, 214413, 2008.
44.
Th. C. Stamatatos, A. Escuer, K. A. Abboud, C. P. Raptopoulou, S. P. Perlepes, G. Christou. Unusual structural types in nickel cluster chemistry from the use of pyridyl oximes: Ni5, Ni12Na2, and Ni14 clusters. Inorganic Chemistry, 47, 11825-11838, 2008.
43.
W. Wernsdorfer, Th. C. Stamatatos, G. Christou. Influence of the Dzyaloshinskii-Moriya exchange interaction on quantum phase interference of spins. Physical Review Letters, 101, 237204, 2008.
42.
C. C. Stoumpos, Th. C. Stamatatos, V. Psycharis, C. P. Raptopoulou, G. Christou, S. P. Perlepes. A new MnII4MnIII4 cluster from the use of methyl 2-pyridyl ketone oxime in manganese carboxylate chemistry: Synthetic, structural and magnetic studies. Polyhedron, 27, 3703-3709, 2008.
41.
Th. C. Stamatatos, V. Nastopoulos, A. J. Tasiopoulos, E. E. Moushi, W. Wernsdorfer, G. Christou, S. P. Perlepes. High nuclearity single-molecule magnets: A mixed-valence Mn26 cluster containing the di-2-pyridylketone diolate dianion, Inorganic Chemistry, 47, 10081-10089, 2008.
40.
Th. C. Stamatatos, A. G. Christou,S. Mukherjee, K. M. Poole, C. Lampropoulos, K. A. Abboud, T. A. O’Brien,G. Christou. High-yield syntheses and reactivity studies of Fe10 ferric wheels: Structural, magnetic, and computational characterization of a star-shaped Fe8 complex. Inorganic Chemistry, 47, 9021-9034, 2008.
39.
Th. C. Stamatatos, K. A. Abboud, G. Christou. Preparation and characterization of new Mn6 and Mn8 clusters obtained from the in situ formation of an unprecedented octadentate ligand. Journal of Molecular Structure, 890, 263-271, 2008.
38.
Th. C. Stamatatos, V. Tangoulis,C. P. Raptopoulou, A. Terzis, G. S. Papaefstathiou, S. P. Perlepes. Di-2-pyridyl ketone/benzoate/azide combination as a source of copper(II) clusters and coordination polymers: Dependence of the product identity on the solvent. Inorganic Chemistry, 47, 7969-7971, 2008.
37.
Th. C. Stamatatos, K. M. Poole,D. Foguet-Albiol,K. A. Abboud, T. A. O’Brien, G. Christou. Spin maximization: Switching of the usual S = 11 state of MnII4MnIII3 disklike complexes to the maximum S = 16. Inorganic Chemistry, 47, 6593-6595, 2008.
36.
Th. C. Stamatatos, K. A. Abboud, W. Wernsdorfer, G. Christou, Covalently linked dimers of clusters: Loop- and dumbbell-shaped Mn24 and Mn26 single-molecule magnets. Angewandte Chemie, International Edition, 47, 6694-6698, 2008.
35.
Th. C. Stamatatos, K. M. Poole, K. A. Abboud, W. Wernsdorfer, T. A. O’Brien,G. Christou. High-spin Mn4 and Mn10 molecules: Large spin changes with structure in mixed-valence MnII4MnIII6 clusters with azide and alkoxide-based ligands. Inorganic Chemistry, 47, 5006-5021, 2008.
34.
T. Taguchi,Th. C. Stamatatos, K. A. Abboud, C. M. Jones, K. M. Poole, T. A. O’Brien, G. Christou. New Fe4, Fe6, and Fe8 clusters of iron(III) from the use of 2-pyridyl alcohols: Structural, magnetic, and computational characterization. Inorganic Chemistry, 47, 4095-4108, 2008.
33.
Th. C. Stamatatos, B. S. Luisi, B. Moulton, G. Christou, Employment of 2,6-diacetylpyridine dioxime as a new route to high nuclearity metal clusters: Mn6 and Mn8 complexes. Inorganic Chemistry, 47, 1134-1144, 2008.
32.
J. Cano, T. Cauchy, E. Ruiz, C. J. Milios, C. C. Stoumpos, Th. C. Stamatatos, S. P. Perlepes, G. Christou, E. K. Brechin. On the origin of ferromagnetism in oximato-based [Mn3O]7+ triangles. Dalton Transactions, 234-240, 2008.
31.
Th. C. Stamatatos,G. Christou. Mixed valency in polynuclear MnII/MnIII, MnIII/MnIV, and MnII/MnIII/MnIV clusters: A foundation for high-spin molecules and single-molecule magnets. Philosophical Transactions of The Royal Society A, 366, 113-125, 2008.
30.
J. T. Brockman,Th. C. Stamatatos,W. Wernsdorfer, K. A. Abboud, G. Christou. Synthesis and characterization of a Mn22 single-molecule magnet and a [Mn22]n single-chain magnet. Inorganic Chemistry, 46, 9160-9171, 2007.
29.
Th. C. Stamatatos, D. Foguet-Albiol, S.- C. Lee, C. C. Stoumpos, C. P. Raptopoulou, A. Terzis, W. Wernsdorfer, S. O. Hill, S. P. Perlepes, G. Christou. Switching on the properties of single-molecule magnetism in triangular manganese(III) complexes. Journal of the American Chemical Society, 129, 9484-9499, 2007.
28.
Th. C. Stamatatos, A. K. Boudalis, K. V. Pringouri,C. P. Raptopoulou, A. Terzis, J. Wolowska, E. J. L. McInnes, S. P. Perlepes. Mixed-valence cobalt(II/III) carboxylate clusters: CoII4CoIII2 and CoIICoIII2 complexes from the use of 2-(hydroxymethyl)pyridine, European Journal of Inorganic Chemistry, 5098-5104, 2007.
27.
Th. C. Stamatatos, G. S. Papaefstathiou, L. R. MacGillivray, A. Escuer, R. Vicente, E. Ruiz, S. P. Perlepes. Ferromagnetic coupling in a 1D coordination polymer containing a symmetric [Cu(m1,1-N3)2Cu(m1,1-N3)2Cu]2+ core and based on an organic ligand obtained from the solid-state. Inorganic Chemistry, 46, 8843-8850, 2007.
26.
Th. C. Stamatatos, K. A. Abboud, S. P. Perlepes, G. Christou. The highest nuclearity metal oxime clusters: Ni14 and Ni12Na2 complexes from the use of 2-pyridinealdoximate and azide ligands. Dalton Transactions, 3861-3863, 2007.
25.
Th. C. Stamatatos, A. G. Christou, C. M. Jones, B. J. O’Callaghan, K. A. Abboud, T. A. O’Brien, G. Christou. Squaring the circle: Molecular squares and rectangles from chelate-induced structural transformations of known Fe10 and new Fe12 ferric wheels. Journal of the American Chemical Society, 129, 9840-9841, 2007.
24.
S.- C. Lee, Th. C. Stamatatos, S. Hill, S. P. Perlepes, G. Christou, High-frequency EPR characterization of a triangular Mn3 single-molecule magnet. Polyhedron, 26, 2225-2229, 2007.
23.
Th. C. Stamatatos, D. Foguet-Albiol, C. C. Stoumpos, C. P. Raptopoulou, A. Terzis, W. Wernsdorfer, S. P. Perlepes,G. Christou. New Mn3 structural motifs in manganese single-molecule magnetism from the use of 2-pyridyloximate ligands. Polyhedron, 26, 2165-2168, 2007.
22.
Th. C. Stamatatos, K. A. Abboud, W. Wernsdorfer, G. Christou. A new Mn25 single-molecule magnet with an S = 61/2 ground state arising from ligand-induced ‘spin-tweaking’ in a high-spin molecule. Polyhedron, 26, 2095-2100, 2007.
21.
G. S. Papaefstathiou, A. K. Boudalis, Th. C. Stamatatos, C. J. Milios, C. G. Efthymiou, C. P. Raptopoulou, A. Terzis, V. Psycharis, Y. Sanakis, R. Vicente, A. Escuer, J.- P. Tuchagues, S. P. Perlepes. A general synthetic route for the preparation of high-spin molecules: Replacement of bridging hydroxo ligands in molecular clusters by end-on azido ligands. Polyhedron, 26, 2089-2094, 2007.
20.
Th. C. Stamatatos, K. A. Abboud, W. Wernsdorfer, G. Christou, Ferromagnetically-coupled decanuclear, mixed-valence [Mn10O4(N3)4(hmp)12]2+ [hmpH = 2-(hydroxymethyl)pyridine] clusters with rare T symmetry and an S = 22 ground state. Polyhedron, 26, 2042-2046, 2007.
19.
Th. C. Stamatatos, C. Papatriantafyllopoulou, E. Katsoulakou, C. P. Raptopoulou, S. P. Perlepes. 2-Pyridyloximate clusters of cobalt and nickel. Polyhedron, 26, 1830-1834, 2007.
18.
Th. C. Stamatatos, K. A. Abboud, W. Wernsdorfer, G. Christou, Spin tweaking of a high-spin molecule: An Mn25 single-molecule magnet with an S = 61/2 ground state. Angewandte Chemie, International Edition,46, 884-888, 2007.
17.
K. V. Pringouri, C. P. Raptopoulou, A. Escuer, Th. C. Stamatatos, Initial use of di-2-pyridyl ketone oxime in chromium carboxylate chemistry: Triangular {CrIII33-O)}7+ compounds and unexpected formation of a carboxylate-free dichromium(II,II) complex, Inorganica Chimica Acta, 360, 69-83, 2007.
16.
Th. C. Stamatatos, E. Diamantopoulou, C. P. Raptopoulou, V. Psycharis, A. Escuer, S. P. Perlepes. Acetate/di-2-pyridyl ketone oximate blend as a source of high-nuclearity nickel(II) clusters: Dependence of the nuclearity on the nature of the inorganic anion present. Inorganic Chemistry, 46, 2350-2352, 2007.
15.
E. E. Moushi, Th. C. Stamatatos, W. Wernsdorfer, V. Nastopoulos, G. Christou, A. J. Tasiopoulos. A family of 3D coordination polymers composed of Mn19 magnetic units. Angewandte Chemie, International Edition,45, 7722-7725, 2006.
14.
P. King, Th. C. Stamatatos, K. A. Abboud, G. Christou. Reversible size modification of iron and gallium molecular wheels: A Ga10 gallic wheel and large Ga18 and Fe18 wheels, Angewandte Chemie, International Edition,45, 7379-7383, 2006.
13.
Th. C. Stamatatos, K. V. Pringouri, C. P. Raptopoulou, R. Vicente, V. Psycharis, A. Escuer, S. P. Perlepes. An unusual dichromium(II,II) compound bearing di-2-pyridyl ketone oximate ligands and prepared by the ligand-assisted reduction of a trichromium(III,III,III) complex in air. Inorganic Chemistry Communications, 9, 1178-1182, 2006.
12.
Th. C. Stamatatos, J. C. Vlahopoulou, Y. Sanakis, C. P. Raptopoulou, V. Psycharis, A. K. Boudalis, S. P. Perlepes, Formation of the {CuII33-OH)}5+ core in copper(II) carboxylate chemistry via use of di-2-pyridyl ketone oxime [(py)2CNOH]: [Cu3(OH)(O2CR)2{(py)2CNO}3] (R = Me, Ph). Inorganic Chemistry Communications, 9, 814-818, 2006.
11.
Th. C. Stamatatos, A. K. Boudalis, Y. Sanakis, C. P. Raptopoulou, Reactivity and structural and physical studies of tetranuclear iron(III) clusters containing the [Fe43-O)2]8+ butterfly core: An FeIII4 cluster with an S = 1 ground state. Inorganic Chemistry, 45, 7372-7381, 2006.
10.
Th. C. Stamatatos, K. A. Abboud, W. Wernsdorfer, G. Christou, High-nuclearity, high-symmetry, high-spin molecules: A mixed-valence Mn10 cage possessing rare T symmetry and an S = 22 ground state. Angewandte Chemie, International Edition, 45, 4134-4137, 2006.
9.
Th. C. Stamatatos, E. Diamantopoulou, A. Tasiopoulos, V. Psycharis, R. Vicente, C. P. Raptopoulou, V. Nastopoulos, A. Escuer, S. P. Perlepes. Enneanuclear Ni(II) complexes from the use of the flexible ligand 2-pyridinealdoxime: The nature of the inorganic anion does not affect the chemical and structural identity of the cationic cluster, Inorganica Chimica Acta, 359, 4149-4157, 2006.
8.
Th. C. Stamatatos, D. Foguet-Albiol, S. P. Perlepes, C. P. Raptopoulou, A. Terzis, C. S. Patrickios, G. Christou, A. J. Tasiopoulos. 4-(Hydroxymethyl)pyridine and pyrimidine in manganese benzoate chemistry: Preparation and characterization of hexanuclear clusters featuring the {MnII4MnIII24-O)2}10+ core, Polyhedron, 25, 1737-1746, 2006.
7.
C. J. Milios, Th. C. Stamatatos, S. P. Perlepes. The coordination chemistry of pyridyl oximes. Polyhedron, 25, 134-194, 2006.
6.
Th. C. Stamatatos, D. Foguet-Albiol,C. C. Stoumpos, C. P. Raptopoulou, A. Terzis, W. Wernsdorfer, S. P. Perlepes, G. Christou. Initial example of a triangular single-molecule magnet from ligand-induced structural distortion of a [MnIII3O]7+ complex, Journal of the American Chemical Society, 127, 15380-15381, 2005.
5.
Th. C. Stamatatos, S. Dionyssopoulou, G. Efthymiou, P. Kyritsis, C. P. Raptopoulou,A. Terzis, R. Vicente, A. Escuer, S. P. Perlepes, The first cobalt metallacrowns: Preparation and characterization of mixed-valence cobalt(II/III), inverse 12-metallacrown-4 complexes. Inorganic Chemistry, 44, 3374-3376, 2005.
4.
Th. C. Stamatatos, A. Bell, P. Cooper, A. Terzis, C. P. Raptopoulou, S. L. Heath, R. E. P. Winpenny, S. P. Perlepes. Old ligands with new coordination chemistry: Linear trinuclear mixed oxidation state cobalt(III/II/III) complexes and their mononuclear ligand cobalt(III) complexes featuring 2-pyridyloximates. Inorganic Chemistry Communications, 8, 533-538, 2005.
3.
K. Skorda, Th. C. Stamatatos, A. P. Vafiadis, A. T. Lithoxoidou, A. Terzis, S. P. Perlepes, J. Mrozinski, C. P. Raptopoulou, J. C. Plakatouras, E. G. Bakalbassis. Copper(II) chloride/1-methylbenzotriazole chemistry: Influence of various synthetic parameters on the product identity, structural and magnetic characterization, and quantum-chemical studies, Inorganica Chimica Acta, 358, 565-582, 2005.
2.
C. J. Milios, Th. C. Stamatatos, P. Kyritsis, A. Terzis, C. P. Raptopoulou, R. Vicente, A. Escuer, S. P. Perlepes. Phenyl 2-pyridyl ketone and its oxime in manganese carboxylate chemistry: Synthesis, characterization, X-ray studies and magnetic properties of mononuclear, trinuclear and octanuclear complexes, European Journal of Inorganic Chemistry, 2885-2901, 2004.
1.
Th. C. Stamatatos, E. Katsoulakou, V. Nastopoulos, C. P. Raptopoulou, E. Manessi-Zoupa, S. P. Perlepes. Cadmium carboxylate chemistry: Preparation, crystal structure, thermal study and spectroscopic characterization of the one-dimensional polymer [Cd(O2CMe)(O2CPh)(H2O)2]n. Zeitschrift für Naturforschung b, 58, 1045-1054, 2003.
 
 

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